Search results for "hot carriers"
showing 2 items of 2 documents
Génération et détection d'électrons chauds dans des dispositifs plasmoniques
2021
Hot carrier-based devices are quite promissing for ultrafast photodetection and toset off enhanced physicochemical reactions. Controlling their generation at the nanoscale within plasmonic devices is a key for the future development of hybrid hot carriers technologies. Indeed, Surface PlasmonPolaritons (SPPs) can be exploited to confine light and enhance the number of excited hot carriers. We aim at studying the excitation and dynamics of hot carriers, enhanced by plasmonics, with two different approaches.In a first approach, we aim at controlling the delocalized generation of hot carriers by a propagative SPP. A plasmonic waveguide with a grating coupler is employed. Hot electrons are indi…
Hot-Carrier Generation in Plasmonic Nanoparticles: The Importance of Atomic Structure
2020
Metal nanoparticles are attractive for plasmon-enhanced generation of hot carriers, which may be harnessed in photochemical reactions. In this work, we analyze the coherent femtosecond dynamics of photon absorption, plasmon formation, and subsequent hot-carrier generation through plasmon dephasing using first-principles simulations. We predict the energetic and spatial hot-carrier distributions in small metal nanoparticles and show that the distribution of hot electrons is very sensitive to the local structure. Our results show that surface sites exhibit enhanced hot-electron generation in comparison to the bulk of the nanoparticle. While the details of the distribution depend on particle s…